Sodium hydroxide, also known as lye and caustic soda,[1][2] is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations Na+ and hydroxide anions OH−.
Sodium hydroxide is a highly corrosive base and alkali that decomposes lipids and proteins at ambient temperatures and may cause severe chemical burns. It is highly soluble in water, and readily absorbs moisture and carbon dioxide from the air. It forms a series of hydrates NaOH·nH2O.[11] The monohydrate NaOH·H2O crystallizes from water solutions between 12.3 and 61.8 °C. The commercially available “sodium hydroxide” is often this monohydrate, and published data may refer to it instead of the anhydrous compound.
As one of the simplest hydroxides, sodium hydroxide is frequently used alongside neutral water and acidic hydrochloric acid to demonstrate the pH scale to chemistry students.[12]
Sodium hydroxide is used in many industries: in the making of wood pulp and paper, textiles, drinking water, soaps and detergents, and as a drain cleaner.
Caustic soda prills, or solid sodium hydroxide in granular or pellet form, are used in various industries for their ease of handling and storage. Here are some common applications:
Caustic soda prills are favored in many industries because they are easier to store and handle compared to the liquid form, and they dissolve readily in water when needed for industrial processes.
Properties | |
Chemical formula | NaOH |
Molar mass | 39.9971 g/mol |
Appearance | White, opaque crystals |
Odor | odorless |
Density | 2.13 g/cm3[4] |
Melting point | 323 °C (613 °F; 596 K)[4] |
Boiling point | 1,388 °C (2,530 °F; 1,661 K)[4] |
Solubility in water | 418 g/L (0 °C) |
1000 g/L (25 °C)[4] | |
3370 g/L (100 °C) | |
Solubility | soluble in glycerol, negligible in ammonia, insoluble in ether, slowly soluble in propylene glycol |
Solubility in methanol | 238 g/L |
Solubility in ethanol | <<139 g/L |
Vapor pressure | <2.4 kPa (20 °C) |
0.1 kPa (700 °C) | |
Acidity (pKa) | 15.7 |
Magnetic susceptibility (χ) | −15.8·10−6 cm3/mol ( |
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